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Article
Characterization of Lifetimes and Mode of Deactivation of Dimensionally Stable Anodes in Current Reverse Applications
Proceedings of the 28th International Mineral Processing Congress (2016, Quebec City, Canada)
  • F. Elnathan
  • Michael S. Moats, Missouri University of Science and Technology
Abstract

The effect of current reversal on two commercially manufactured electrodes (RuO2-TiO2 and IrO2-Ta2O5 coated Ti) in a chloride bearing electrolyte was evaluated. Accelerated lifetimes were found to decrease with increasing current density and increasing reversal frequency. Ru: Ti coated electrodes exhibited longer lifetimes than Ir: Ta coated electrodes even though they had one-third as much precious metal content. Chloride concentration did not affect lifetime in the range examined. Using energy dispersive X-ray spectroscopy (EDS), scanning electron microscopy (SEM) and electrochemical impedance spectroscopy (EIS), the failure mode of the electrodes was determined to be coating dissolution leading ultimately to passivation by the presumed growth of a highly resistive oxide at the coating/substrate interface.

Meeting Name
28th International Mineral Processing Congress, IMPC 2016 (2016: Sep. 11-16, Quebec City, Canada)
Department(s)
Materials Science and Engineering
Keywords and Phrases
  • Catalytic titanium anodes,
  • Current reversal,
  • IrO2-Ta2O5,
  • Lifetimes,
  • RuO2-TiO2
International Standard Book Number (ISBN)
978-192687229-2
Document Type
Article - Conference proceedings
Document Version
Citation
File Type
text
Language(s)
English
Rights
© 2016 TAPPI Press, All rights reserved.
Publication Date
9-1-2016
Publication Date
01 Sep 2016
Citation Information
F. Elnathan and Michael S. Moats. "Characterization of Lifetimes and Mode of Deactivation of Dimensionally Stable Anodes in Current Reverse Applications" Proceedings of the 28th International Mineral Processing Congress (2016, Quebec City, Canada) (2016)
Available at: http://works.bepress.com/michael-moats/34/