SelectedWorks - Fernande Grandjean

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Selected Works of Fernande Grandjean

Adjunct Faculty Member

Dr. Fernande Grandjean is an Adjunct Professor in the department of Chemistry at Missouri University of Science and Technology. She has a Ph.D. from the University of Liège.

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About Fernande Grandjean

Dr. Fernande Grandjean is an Adjunct Professor in the department of Chemistry at Missouri University of Science and Technology. She has a Ph.D. from the University of Liège.

Present	Adjunct Faculty Member, Missouri University of Science and Technology ‐ Chemistry
Institution Organization Position Type Position Title Time Period to Options Current Position Affiliate my profile with this Institution

Chemistry and Inorganic Chemistry

The study of the electronic properties of solid state materials by Mössbauer and X-ray absorption spectroscopy and The study of the magnetic and thermoelectric materials, minerals, metallic nanopowders, and spin-state crossover complexes

1973	Ph.D., University of Liège
Institution Organization Student Type Student Title Degree Time Period to Options Currently enrolled Affiliate my profile with this Institution

Scopus Author Profile

Mössbauer Spectral Studies of Iron Phosphate Containing Minerals and Compounds

Mössbauer Spectroscopy: Applications in Chemistry and Materials Science (2023)

Gary J. Long and Fernande Grandjean

This Chapter Presents a Detailed Discussion of the Mössbauer Spectra of Iron Phosphate Containing Compounds and Minerals - Compounds that ...

Further Comments on "Engineering Shape Anisotropy of Fe3o4-Γ-Fe2o3hollow Nanoparticles for ...

ACS Applied Nano Materials (2022)

Fernande Grandjean and Gary J. Long

In their earlier paper, Niraula et al. (ACS Appl. Nano Mater. 2021, 4, 3148-3158) described the morphological, compositional, and magnetic ...

Synthesis, Physicochemical Characterization, and Catalytic Evaluation of Fe3+-Containing SSZ-70 ...

ACS Catalysis (2022)

Christopher M. Lew, Cong Yan Chen, Gary J. Long, Fernande Grandjean, et al.

Whereas one-dimensional, 10-membered ring zeolites are typically used for hydroisomerization, Fe3+-containing SSZ-70 (Fe-SSZ-70) shows remarkable isomerization selectivity for a zeolite ...

Synthesis, Physicochemical Characterization, and Catalytic Evaluation of Fe³⁺-Containing SSZ-70 ...

ACS Catalysis (2022)

Christopher M. Lew, Cong Yan Chen, Gary J. Long, Fernande Grandjean, et al.

Whereas one-dimensional, 10-membered ring zeolites are typically used for hydroisomerization, Fe3+-containing SSZ-70 (Fe-SSZ-70) shows remarkable isomerization selectivity for a zeolite ...

Best Practices and Protocols in Mössbauer Spectroscopy

Chemistry of Materials (2021)

Fernande Grandjean and Gary J. Long

Over the past 50 years or so, the authors have written and reviewed many papers dealing with Mössbauer spectral research ...

Impact of Lithium and Potassium Cations on the Mössbauer Spectral ...

Chemistry of Materials (2020)

Fernande Grandjean, Gary J. Long, Roger Evrard, U. Chan Chung, et al.

Based on the combined corrected chemical analysis, the single-crystal X-ray structural results, and the revised Mössbauer spectral analysis, the best ...

Correction to Two Acentric Mononuclear Molecular Complexes with Unusual Magnetic ...

Inorganic Chemistry (2020)

Fang-Hua Zhao, Yun-Xia Che, Jimin Zheng, Fernande Grandjean, et al.

This erratum corrects Two Acentric Mononuclear Molecular Complexes with Unusual Magnetic and Ferroelectric Properties .

Revealing the Hidden Hyperfine Interactions in ϵ-Iron

Physical Review B (2020)

Dimitrios Bessas, Ilya Sergueev, Konstantin Glazyrin, Cornelius Strohm, et al.

Herein, evidence for the long-sought finite hyperfine interaction in the high-pressure hexagonal close-packed ε-iron is gained through synchrotron radiation perturbed ...

Confinement of Atomically Defined Metal Halide Sheets in a Metal-Organic ...

Miguel I. Gonzalez, Ari B. Turkiewicz, Lucy E. Darago, Julia Oktawiec, et al.

The size-dependent and shape-dependent characteristics that distinguish nanoscale materials from bulk solids arise from constraining the dimensionality of an inorganic ...

Mössbauer Spectral Study of the Low-Temperature Electronic and Magnetic Properties ...

Inorganic Chemistry (2019)

Fernande Grandjean and Gary J. Long

The Mössbauer spectra of trigonal α-FePO4, measured between 4.2 and 300 K, exhibit hyperfine parameters characteristic of high-spin iron(III) in ...

Iron Detection and Remediation with a Functionalized Porous Polymer Applied ...

Chemical Science (2019)

Sumin Lee, Adam Uliana, Mercedes K. Taylor, Gary J. Long, et al.

Iron is one of the most abundant elements in the environment and in the human body. As an essential nutrient, ...

Synthesis, Structure and Magnetic Properties of an Unusual Oligonuclear Iron ...

Polyhedron (2019)

F. Setifi, Z. Setifi, P. Konieczny, C. Glidewell, et al.

The synthesis, characterization, structure and magnetic properties of a hexametallic mixed-metal iron(III)-cobalt(III) compound are described. The compound has been characterized ...

Charge Delocalization and Bulk Electronic Conductivity in the Mixed-Valence Metal-Organic ...

Journal of the American Chemical Society (2018)

Jesse G. Park, Michael L. Aubrey, Julia Oktawiec, Khetpakorn Chakarawet, et al.

Metal-organic frameworks are of interest for use in a variety of electrochemical and electronic applications, although a detailed understanding of ...

Electron Delocalization and Charge Mobility as a Function of Reduction ...

Nature Materials (2018)

Michael L. Aubrey, Brian M. Wiers, Sean C. Andrews, Tsuneaki Sakurai, et al.

Conductive metal-organic frameworks are an emerging class of three-dimensional architectures with degrees of modularity, synthetic flexibility and structural predictability that ...

Effect of Defect Site Preorganization on Fe(III) Grafting and ...

Chemistry of Materials (2017)

Nicolas A. Grosso-Giordano, Alexander J. Yeh, Alexander Okrut, Diane J. Xiao, et al.

The stabilization of isolated grafted Fe3+ sites on siliceous supports is investigated by a comparative study of crystalline versus amorphous ...

Search for Electron Delocalization from [Fe(CN)₆]³ˉ to ...

Inorganic Chemistry (2017)

Ahmed S. Abouelwafa, Andreas Hauser, Valeriu Mereacre, Yanhua Lan, et al.

K3Fe(CN)6 reacts with the viologen 1,1′-bis(2,4-dinitrophenyl)-4,4′-bipyridinium dication, (DNP)2+, to form a supramolecular complex, (DNP)3[Fe(CN)6]2·10H2O (1). The crystal structure of 1 ...

Characterization and Utilization of Prussian Blue and Its Pigments

Dalton Transactions (2016)

Fernande Grandjean, Louise Samain and Gary J. Long

This review deals with our long-range goal of determining why the Prussian blue pigments, typically either the "soluble" KFeIII[FeII(CN)6]·xH2O or ...

Comment on "Calibration of ⁵⁷Fe Mössbauer constants by first principles ...

Physical Chemistry Chemical Physics (2016)

Fernande Grandjean and Gary J. Long

The proportionality constant, α, between the observed isomer shifts and the calculated electron probability density at the iron nucleus has ...

Reversible CO Scavenging via Adsorbate-Dependent Spin State Transitions in an ...

Journal of the American Chemical Society (2016)

Douglas A. Reed, Dianne J. Xiao, Miguel I. Gonzalez, Lucy E. Darago, et al.

A new metal-organic framework, Fe-BTTri (Fe3[(Fe4Cl)3(BTTri)8]2·18CH3OH, H3BTTri =1,3,5-tris(1H- 1,2,3-triazol-5-yl)benzene)), is found to be highly selective in the adsorption of CO ...

Mössbauer Spectral Properties of Yttrium Iron Garnet, Y₃Fe₅O₁₂, and Its ...

Inorganic Chemistry (2016)

Gary J. Long, Fernande Grandjean, Xiaofeng Guo, Alexandra Navrotsky, et al.

Several high-resolution Mössbauer spectra of yttrium iron garnet, Y3Fe5O12, have been fit as a function of temperature with a new ...

Electron Hopping through Double-Exchange Coupling in a Mixed-Valence Diiminobenzoquinone-Bridged Fe₂ ...

Journal of the American Chemical Society (2015)

Alexandra I. Gaudette, Ie Rang Jeon, John Stuart Anderson, Fernande Grandjean, et al.

The ability of a benzoquinonoid bridging ligand to mediate double-exchange coupling in a mixed-valence Fe2 complex is demonstrated. Metalation of ...

The Instability of Ni{N(SiMe₃)₂}₂: A Fifty ...

Angewandte Chemie International Edition (2015)

Michelle A. Faust, Aimee M. Bryan, Akseli Mansikkamäki, Petra Vasko, et al.

The characterization of the unstable NiII bis(silylamide) Ni{N(SiMe3)2}2 (1), its THF complex Ni{N(SiMe3)2}2(THF) (2), and the stable bis(pyridine) derivative trans-Ni{N(SiMe3)2}2(py)2 ...

Combined Mössbauer Spectral and Density Functional Study of an Eight-Coordinate ...

Inorganic Chemistry (2015)

Gary J. Long, Fernande Grandjean, Todd C. Harrop, Heather M. Petroccia, et al.

The iron-57 Mössbauer spectra of the eight-coordinate complex, [Fe(LN4)2](BF4)2, where LN4 is the tetradentate N1(E),N2(E)-bis[(1-methyl-1H-imidazol-2-yl)methylene]-1,2-benzenediimine ligand, have been measured between ...

Quasi-Three-Coordinate Iron and Cobalt Terphenoxide Complexes {AriPr8OM(-O)}₂ (AriPr8 ...

Inorganic Chemistry (2015)

Pei Zhao, Hao Lei, Chengbao Ni, Jingdong Guo, et al.

The bis(-oxo) dimeric complexes {AriPr8OM(-O)}2 (AriPr8 = C6H-2,6-(C6H2-2,4,6-iPr3)2-3,5-iPr2; M = Fe (1), Co (2)) were prepared by oxidation of the ...

Salts of the Two-coordinate Homoleptic Manganese(I) Dialkyl Anion [Mn ...

Chemical Communications (2015)

Chun-Yi Lin, James C. Fettinger, Nicholas F. Chilton, Alasdair Formanuik, et al.

The reduction of Mn{C(SiMe3)3}2 with KC8 in the presence of crown ethers yielded the d6, Mn(i) salts [K2(18-crown-6)3][Mn{C(SiMe3)3}2]2 and [K(15-crown-5)2][Mn{C(SiMe3)3}2], ...