Article
Preparation of Phosphonoterephthalic Acids via Palladium-catalyzed Coupling of Aromatic Iodoesters
Synthetic Communications
Document Type
Article
Publication Date
1-1-2013
Abstract
The current article reports in detail the preparation of two phosphonoterephthalic acids: 2-phosphonoterephthalic acid (1) and 2,5-diphosphonoterephthalic acid (2). Efficient, scalable syntheses have been developed for both compounds based on Pd-catalyzed coupling reactions of iodinated terephthalate esters. Phosphonoterephthalic acids are potentially useful as flame-retardant additives or as monomers for the construction of acid-pendant polymer chains.
Inclusive pages
1831-1836
ISBN/ISSN
0039-7911
Document Version
Postprint
Copyright
Copyright © 2013, Taylor & Francis
Publisher
Taylor & Francis
Peer Reviewed
Yes
Disciplines
- Analytical Chemistry,
- Biochemical Phenomena, Metabolism, and Nutrition,
- Chemical and Pharmacologic Phenomena,
- Chemistry,
- Environmental Chemistry,
- Inorganic Chemistry,
- Materials Chemistry,
- Medical Biochemistry,
- Medicinal-Pharmaceutical Chemistry,
- Organic Chemistry,
- Other Chemistry and
- Physical Chemistry
Citation Information
Nathaniel Ivan, Vladimir Benin and Alexander Morgan. "Preparation of Phosphonoterephthalic Acids via Palladium-catalyzed Coupling of Aromatic Iodoesters" Synthetic Communications Vol. 43 Iss. 13 (2013) Available at: http://works.bepress.com/vladimir_benin/11/
The document available for download is the authors' accepted manuscript, posted here in compliance with the publisher's policy on self-archiving. Some differences may exist between this version and the publisher's version; as such, researchers wishing to quote directly from it are advised to consult the version of record, available at many libraries or from the publisher: http://dx.doi.org/10.1080/00397911.2012.673448
Permission documentation is on file.