Skip to main content
Article
Liquid Phase Stability under an Extreme Temperature Gradient
Physical Review Letters
  • Zhi Liang, Missouri University of Science and Technology
  • Kiran Sasikumar
  • Pawel Keblinski
Abstract

Using Nonequilibrium Molecular Dynamics Simulations, We Subject Bulk Liquid to a Very High-Temperature Gradient and Observe a Stable Liquid Phase with a Local Temperature Well above the Boiling Point. Also, under This High-Temperature Gradient, the Vapor Phase Exhibits Condensation into a Liquid at a Temperature Higher Than the Saturation Temperature, Indicating that the Observed Liquid Stability is Not Caused by Nucleation Barrier Kinetics. We Show that, Assuming Local Thermal Equilibrium, the Phase Change Can Be Understood from the Thermodynamic Analysis. the Observed Elevation of the Boiling Point is Associated with the Interplay between the "Bulk" Driving Force for the Phase Change and Surface Tension of the Liquid-Vapor Interface that Suppresses the Transformation. This Phenomenon is Analogous to that Observed for Liquids in Confined Geometries. in Our Study, However, a Low-Temperature Liquid, Rather Than a Solid, Confines the High-Temperature Liquid. © 2013 American Physical Society.

Department(s)
Mechanical and Aerospace Engineering
Comments

National Science Foundation, Grant CBET-1033354

Document Type
Article - Journal
Document Version
Final Version
File Type
text
Language(s)
English
Rights
© 2023 American Physical Society, All rights reserved.
Publication Date
11-25-2013
Publication Date
25 Nov 2013
Citation Information
Zhi Liang, Kiran Sasikumar and Pawel Keblinski. "Liquid Phase Stability under an Extreme Temperature Gradient" Physical Review Letters Vol. 111 Iss. 22 (2013) ISSN: 1079-7114; 0031-9007
Available at: http://works.bepress.com/zhi-liang/26/