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Article
Strain Phase Separation: Formation of Ferroelastic Domain Structures
Physical Review B
  • Fei Xue
  • Yongjun Li
  • Yijia Gu, Missouri University of Science and Technology
  • Jinxing Zhang
  • Long-Qing Chen
Abstract

Phase decomposition is a well-known process leading to the formation of two-phase mixtures. Here we show that a strain imposed on a ferroelastic crystal promotes the formation of mixed phases and domains, i.e., strain phase separation with local strains determined by a common tangent construction on the free energy versus strain curves. It is demonstrated that a domain structure can be understood using the concepts of domain/phase rule, lever rule, and coherent and incoherent strain phase separation, in a complete analogy to phase decomposition. The proposed strain phase separation model is validated using phase-field simulations and experimental observations of PbTiO3 and BiFeO3 thin films as examples. The proposed model provides a simple tool to guide and design domain structures of ferroelastic systems.

Department(s)
Materials Science and Engineering
Comments
The work at Penn State is supported by the U.S. Department of Energy, Office of Basic Energy Sciences, Division of Materials Sciences and Engineering under Award FG02-07ER46417 (F.X. and L.-Q.C.) and by the NSF MRSEC under Grant No. DMR-1420620 (F.X. and Y.G.). The work at Beijing Normal University is supported by the NSFC under Contract No. 51322207 and the National Key Research and Development Program of China under Contract No. 2016YFA0302300. This research used resources of the National Energy Research Scientific Computing Center, a DOE Office of Science User Facility supported by the Office of Science of the U.S. Department of Energy under Contract No. DE-AC02-05CH11231.
Document Type
Article - Journal
Document Version
Final Version
File Type
text
Language(s)
English
Rights
© 2016 American Physical Society (APS), All rights reserved.
Publication Date
12-1-2016
Publication Date
01 Dec 2016
Disciplines
Citation Information
Fei Xue, Yongjun Li, Yijia Gu, Jinxing Zhang, et al.. "Strain Phase Separation: Formation of Ferroelastic Domain Structures" Physical Review B Vol. 94 Iss. 22 (2016) ISSN: 2469-9950; 2469-9969
Available at: http://works.bepress.com/yijia-gu/69/