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Selected Works of Yana Sandlers
Article
Electrophilicity-Nucleophilicity Scale Also in the Gas Phase
Angewandte Chemie - International Edition
  • Chagit Denekamp, Technion - Israel Institute of Technology
  • Yana Sandlers, Technion - Israel Institute of Technology
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Document Type
Article
Publication Date
3-20-2006
Disciplines
Abstract

Changing the state: The electrophilicity of benzhydryl cations (see formula) towards neutral amine nucleophiles in the gas phase was determined. It was found that the kinetics of electrophile-nucleophile gas-phase reactions correlate well with values known in solution although the actual electrophilicity parameters are considerably smaller in the gas phase. (Chemical Equation Presented) © 2006 Wiley-VCH Verlag GmbH & Co. KGaA.

DOI
10.1002/anie.200503235
Citation Information
Chagit Denekamp and Yana Sandlers. "Electrophilicity-Nucleophilicity Scale Also in the Gas Phase" Angewandte Chemie - International Edition Vol. 45 Iss. 13 (2006) p. 2093 - 2096 ISSN: 14337851
Available at: http://works.bepress.com/yana-sandlers/8/