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Article
Experimental and Theoretical Investigations of Solvation Dynamics of Ionic Fluids:  Appropriateness of Dielectric Theory and the Role of DC Conductivity
Journal of Physical Chemistry A
  • Mintu Halder, Iowa State University
  • Lindsay Elizabeth Sanders Headley, Iowa State University
  • Prasun Mukherjee, Iowa State University
  • Xueyu Song, Iowa State University
  • Jacob W. Petrich, Iowa State University
Document Type
Article
Disciplines
Publication Version
Published Version
Publication Date
6-20-2006
DOI
10.1021/jp062936l
Abstract

An analysis is provided of the subnanosecond dynamic solvation of ionic liquids in particular and ionic solutions in general. It is our hypothesis that solvation relaxation in ionic fluids, in the nonglassy and nonsupercooled regimes, can be understood rather simply in terms of the dielectric spectra of the solvent. This idea is suggested by the comparison of imidazolium ionic liquids with their pure organic counterpart, butylimidazole (J. Phys. Chem. B 2004, 108, 10245−10255). It is borne out by a calculation of the solvation correlation time from frequency dependent dielectric data for the ionic liquid, ethylammonium nitrate, and for the electrolyte solution of methanol and sodium perchlorate. Very good agreement is obtained between these theoretically calculated solvation relaxation functions and those obtained from fluorescence upconversion spectroscopy. Our comparisons suggest that translational motion of ions may not be the predominant factor in short-time solvation of ionic fluids and that many tools and ideas about solvation dynamics in polar solvents can be adapted to ionic fluids.

Comments

Reprinted (adapted) with permission from Journal of Physical Chemistry A 110 (2006): 8623, doi: 10.1021/jp062936l. Copyright 2006 American Chemical Society.

Copyright Owner
American Chemical Society
Language
en
File Format
application/pdf
Citation Information
Mintu Halder, Lindsay Elizabeth Sanders Headley, Prasun Mukherjee, Xueyu Song, et al.. "Experimental and Theoretical Investigations of Solvation Dynamics of Ionic Fluids:  Appropriateness of Dielectric Theory and the Role of DC Conductivity" Journal of Physical Chemistry A Vol. 110 Iss. 28 (2006) p. 8623 - 8626
Available at: http://works.bepress.com/xueyu-song/29/