Strain and Huckel Aromaticity: Driving Forces for a Promising New Generation of Electron Acceptors in Organic ElectronicsPolymer Engineering Faculty Research
AbstractStraining at the leash: The main features of electron-accepting materials with a 9,9′-bifluorenylidene backbone are strain relief and a gain in aromaticity. These dimers (see picture) exhibit absorption near the red spectral region (ca. 600 nm) and HOMO (5.58–5.06 eV) and LUMO (3.37–3.09 eV) energy levels, which, together with high solubility and thermal stability render these materials attractive acceptors for bulk heterojunction (BHJ) solar cells.
Citation InformationXiong Gong. "Strain and Huckel Aromaticity: Driving Forces for a Promising New Generation of Electron Acceptors in Organic Electronics" Vol. 49 (2009) p. 532 - 536
Available at: http://works.bepress.com/xiong_gong/126/