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Polarization alignment, phase transition, and piezoelectricity development in polycrystalline 0.5Ba(Zr0.2 Ti0.8)O3-0.5(Ba0.7 Ca0.3)TiO3
Australian Institute for Innovative Materials - Papers
  • Hanzheng Guo, Iowa State University
  • Brian K Voas, Iowa State University
  • Shujun Zhang, The Pennsylvania State University
  • Chao Zhou, Xi'an Jiaotong University
  • Xiaobing Ren, Xi'an Jiaotong University
  • Scott P Beckman, Iowa State University
  • Xiaoli Tan, Iowa State University
RIS ID
106050
Publication Date
1-1-2014
Publication Details

Guo, H., Voas, B. K., Zhang, S., Zhou, C., Ren, X., Beckman, S. P. & Tan, X. (2014). Polarization alignment, phase transition, and piezoelectricity development in polycrystalline 0.5Ba(Zr0.2 Ti0.8)O3-0.5(Ba0.7 Ca0.3)TiO3. Physical Review B: Condensed Matter and Materials Physics, 90 (1), 014103-1-014103-10.

Abstract
The microstructural origin of the exceptionally high piezoelectric response of polycrystalline 0.5Ba(Zr0.2Ti0.8)O3-0.5(Ba0.7Ca0.3)TiO3 is investigated using in situ transmission electron microscopy, in addition to a wide variety of bulk measurements and first-principles calculations. A direct correlation is established relating a domain wall-free state to the ultrahigh piezoelectric d33 coefficient in this BaTiO3-based composition. The results suggest that the unique single-domain state formed during electrical poling is a result of a structural transition from coexistent rhombohedral and tetragonal phases to an orthorhombic phase that has an anomalously low elastic modulus. First-principles calculations indicate that incorporating Ca2+ and Zr4+ into BaTiO3 reduces the differences in structure and energy of the variant perovskite phases, and 0.5Ba(Zr0.2Ti0.8)O3-0.5(Ba0.7Ca0.3)TiO3 is identified as unique because the variant phases become almost indistinguishable. The structural instability and elastic softening observed here are responsible for the excellent piezoelectric properties of this lead-free ceramic. 2014 American Physical Society.
Citation Information
Hanzheng Guo, Brian K Voas, Shujun Zhang, Chao Zhou, et al.. "Polarization alignment, phase transition, and piezoelectricity development in polycrystalline 0.5Ba(Zr0.2 Ti0.8)O3-0.5(Ba0.7 Ca0.3)TiO3" (2014)
Available at: http://works.bepress.com/xiaoli_tan/77/