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Article
Fine‐Structure Mixing Within the Zn(43PJ) Multiplet by Collisions with the Noble Gases
The Journal of Chemical Physics
  • Xianming Han, Butler University
  • J. F. Kelly
Document Type
Article
Publication Date
1-1-1991
DOI
http://dx.doi.org/10.1063/1.460483
Abstract
Measurements of rate coefficients for intramultiplet state transfer of Zn(4 3 P 1→4 3 P J’) by collisions with the rare gases are presented. The state‐to‐state binary rate coefficients are derived from least‐squares fittings of the time‐resolved triexponential behavior of the 4 3 P 1fluorescence. These rate coefficients were studied systematically over a temperature range of 690–1100 K in order to characterize the velocity dependence of the collisional coupling. The systematic behavior of the rate coefficients with varying temperature and noble gas species is qualitatively consistent with a nearly adiabatic coupling limit for noncrossing levels.
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Citation Information
Xianming Han and J. F. Kelly. "Fine‐Structure Mixing Within the Zn(43PJ) Multiplet by Collisions with the Noble Gases" The Journal of Chemical Physics Vol. 94 (1991)
Available at: http://works.bepress.com/xianming_han/17/