Article
Transitions and Relaxations in Cis Polypentenamer and Its Hydrogenated Derivatives
Macromolecules
(1977)
Abstract
A study has been made of the dynamic mechanical relaxation behavior of a 97% cis polypentenamer and its hydrogenated derivatives. The starting polypentenamer is wholly amorphous and derivatives were synthesized having melting points from -11 to 131 °C and degrees of crystallinity from 2 to 80%. Three relaxations are discernible in the temperature range from -160 °C to the melting point and these are labeled a, {3, and 1' in order of decreasing temperature. The a relaxation occurs only in the crystalline derivatives. In the derivatives of low crystallinity, it originates from motions accompanying melting; in derivatives of high crystallinity, it originates from a combination of intracrystalline motions and interlamellar slip. The f3 relaxation arises from microbrownian motion accompanying the glass transition. It decreases in temperature initially as double bonds are converted to single bonds but shows an abrupt rise in temperature at the first trace of crystallinity and continues to rise thereafter. The 1' relaxation is absent in the starting polypentenamer but is present in all the derivatives. It increases in magnitude with increasing CH2 sequence length and with crystallinity. It arises from a crankshaft motion in the amorphous phase involving a few CH2 units and motion in the crystal phase probably at chain end defects. It is suggested that the twophase model is only applicable to polymers with amorphous phases of sufficiently different structure from the crystalline phases as to preclude the crystallization of the amorphous phase under any circumstances.
Keywords
- Transitions,
- Relaxations,
- Sic Polypentenamer,
- Hydrogenated Derivative
Disciplines
Publication Date
1977
Citation Information
William MacKnight and T. R. Earnest. "Transitions and Relaxations in Cis Polypentenamer and Its Hydrogenated Derivatives" Macromolecules Vol. 10 (1977) p. 206 - 210 Available at: http://works.bepress.com/william_macknight/54/