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Article
Boro/carbothermal Reduction Co-Synthesis of Dual-Phase High-Entropy Boride-Carbide Ceramics
Journal of the European Ceramic Society
  • Lun Feng
  • William Fahrenholtz, Missouri University of Science and Technology
  • Gregory E. Hilmas
  • Stefano Curtarolo
Abstract

Dense, dual-phase (Cr,Hf,Nb,Ta,Ti,Zr)B2-(Cr,Hf,Nb,Ta,Ti,Zr)C ceramics were synthesized by boro/carbothermal reduction of oxides and densified by spark plasma sintering. The high-entropy carbide content was about 14.5 wt%. Grain growth was suppressed by the pinning effect of the two-phase ceramic, which resulted in average grain sizes of 2.7 ± 1.3 µm for the high-entropy boride phase and 1.6 ± 0.7 µm for the high-entropy carbide phase. Vickers hardness values increased from 25.2 ± 1.1 GPa for an indentation load of 9.81 N to 38.9 ± 2.5 GPa for an indentation load of 0.49 N due to the indentation size effect. Boro/carbothermal reduction is a facile process for the synthesis and densification of dual-phase high entropy boride-carbide ceramics with both different combinations of transition metals and different proportions of boride and carbide phases.

Department(s)
Materials Science and Engineering
Comments

Office of Naval Research, Grant N00014-21-1-2515

Keywords and Phrases
  • High-Entropy Boride,
  • High-Entropy Carbide,
  • Microstructure,
  • Ultra-High Temperature Ceramics,
  • Vickers Hardness
Document Type
Article - Journal
Document Version
Final Version
File Type
text
Language(s)
English
Rights
© 2023 Elsevier, All rights reserved.
Publication Date
1-1-2023
Publication Date
01 Jan 2023
Citation Information
Lun Feng, William Fahrenholtz, Gregory E. Hilmas and Stefano Curtarolo. "Boro/carbothermal Reduction Co-Synthesis of Dual-Phase High-Entropy Boride-Carbide Ceramics" Journal of the European Ceramic Society (2023) ISSN: 1873-619X; 0955-2219
Available at: http://works.bepress.com/william-fahrenholtz/310/