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Article
Surface-Mediated Hyperpolarization of Liquid Water from Parahydrogen
Ames Laboratory Accepted Manuscripts
  • Evan Wenbo Zhao, University of Florida
  • Raghu V. Maligal-Ganesh, Iowa State University
  • Yong Du, University of Florida
  • Tommy Yunpu Zhao, University of Florida
  • James Collins, McKnight Brain Institute
  • Tao Ma, Ames Laboratory
  • Lin Zhou, Ames Laboratory
  • Tian Wei Goh, Iowa State University
  • Wenyu Huang, Iowa State University and Ames Laboratory
  • Clifford R. Bowers, University of Florida
Publication Date
6-14-2018
Department
Ames Laboratory; Chemistry
Report Number
IS-J 9724
DOI
10.1016/j.chempr.2018.03.004
Journal Title
Chem
Abstract

This article reports the discovery of surface-mediated parahydrogen-induced alignment of the proton magnetic moments in liquid water as well as methanol and ethanol. In this SWAMP (surface waters are magnetized by parahydrogen) effect, the spin polarization of the solvent protons is enhanced simply by the bubbling of parahydrogen through a suspension of Pt3Sn intermetallic nanoparticles (iNPs) encapsulated within a protectective mesoporous silica shell (Pt3Sn@mSiO2). The conversion of singlet spin order into magnetization is mediated by symmetry-breaking interactions on the surface of the iNPs. Stimulated emission NMR signals of the exchangeable hydroxy protons are observed. Non-exchangeable methyl or methylene protons are also hyperpolarized, an observation that provides insight into the molecular mechanism. SWAMP has a myriad of potential applications, ranging from low-field MRI to drug discovery.

Language
en
Publisher
Iowa State University Digital Repository, Ames IA (United States)
Citation Information
Evan Wenbo Zhao, Raghu V. Maligal-Ganesh, Yong Du, Tommy Yunpu Zhao, et al.. "Surface-Mediated Hyperpolarization of Liquid Water from Parahydrogen" Vol. 4 Iss. 6 (2018) p. 1387 - 1403
Available at: http://works.bepress.com/wenyu_huang/49/