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Metal–Organic‐Framework‐Derived Carbons: Applications as Solid‐Base Catalyst and Support for Pd Nanoparticles in Tandem Catalysis
Chemistry - A European Journal
  • Xinle Li, Iowa State University and Ames Laboratory
  • Biying Zhang, Iowa State University and Ames Laboratory
  • Yuhui Fang, Beijing Normal University
  • Weijun Sun, Iowa State University and Ames Laboratory
  • Zhiyuan Qi, Iowa State University and Ames Laboratory
  • Yuchen Pei, Iowa State University and Ames Laboratory
  • Shuyan Qi, Beijing Normal University
  • Pengyu Yuan, Iowa State University
  • Xuechen Luan, Iowa State University and Ames Laboratory
  • Tian Wei Goh, Iowa State University and Ames Laboratory
  • Wenyu Huang, Iowa State University and Ames Laboratory
Document Type
Article
Publication Version
Accepted Manuscript
Publication Date
3-29-2017
DOI
10.1002/chem.201605852
Abstract

The facile pyrolysis of a bipyridyl metal‐organic framework, MOF‐253, produces N‐doped porous carbons (Cz‐MOF‐253), which exhibit excellent catalytic activity in the Knoevenagel condensation reaction and outperform other nitrogen‐containing MOF‐derived carbons. More importantly, by virtue of their high Lewis basicity and porous nature, Cz‐MOF‐253‐supported Pd nanoparticles (Pd/Cz‐MOF‐253‐800) show excellent performance in a one‐pot sequential Knoevenagel condensation‐hydrogenation reaction.

Comments

This is the peer-reviewed version of the following article: Li, Xinle, Biying Zhang, Yuhui Fang, Weijun Sun, Zhiyuan Qi, Yuchen Pei, Shuyan Qi et al. "Metal–Organic‐Framework‐Derived Carbons: Applications as Solid‐Base Catalyst and Support for Pd Nanoparticles in Tandem Catalysis." Chemistry-A European Journal 23, no. 18 (2017): 4266-4270, which has been published in final form at doi: 10.1002/chem.201605852. This article may be used for non-commercial purposes in accordance with Wiley Terms and Conditions for Self-Archiving. Posted with permission.

Copyright Owner
Wiley‐VCH Verlag GmbH & Co. KGaA, Weinheim
Language
en
File Format
application/pdf
Citation Information
Xinle Li, Biying Zhang, Yuhui Fang, Weijun Sun, et al.. "Metal–Organic‐Framework‐Derived Carbons: Applications as Solid‐Base Catalyst and Support for Pd Nanoparticles in Tandem Catalysis" Chemistry - A European Journal Vol. 23 Iss. 18 (2017) p. 4266 - 4270
Available at: http://works.bepress.com/wenyu_huang/45/