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Article
A Three-Dimensional Microporous Metal–Metalloporphyrin Framework
Inorganic Chemistry
  • Zhiyong Guo, University of Texas at San Antonio
  • Dan Yan, University of Texas at San Antonio
  • Hailong Wang, University of Texas at San Antonio
  • Daniel Tesfagaber, Iowa State University
  • Xinle Li, Iowa State University
  • Yusheng Chen, University of Chicago
  • Wenyu Huang, Iowa State University
  • Banglin Chen, University of Texas at San Antonio
Document Type
Article
Publication Version
Published Version
Publication Date
1-1-2015
DOI
10.1021/ic502116k
Abstract
A new porphyrin-based microporous MOF, {Mn(II)0.5[Mn(II)4Cl(Mn(III)Cl-ttzpp)2(H2O)4]}·(DEF)20·(CH3OH)18·(H2O)12 (UTSA-57), has been constructed from {5,10,15,20-tetrakis[4-(2,3,4,5-tetrazolyl)phenyl]porphyrinato} manganese(III) chloride as the metalloligand. The MOF adopts the rare scu topology with one-dimensional square nanotube-like channels of about 20 Å. UTSA-57a exhibits permanent porosity and displays moderately high performance for C2H2/CH4 separation at room temperature.
Comments

Reprinted (adapted) with permission from Inorg. Chem., 2015, 54 (1), pp 200–204. Copyright 2015 American Chemical Society

Copyright Owner
American Chemical Society
Language
en
File Format
application/pdf
Citation Information
Zhiyong Guo, Dan Yan, Hailong Wang, Daniel Tesfagaber, et al.. "A Three-Dimensional Microporous Metal–Metalloporphyrin Framework" Inorganic Chemistry Vol. 54 Iss. 1 (2015) p. 200 - 204
Available at: http://works.bepress.com/wenyu_huang/4/