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Article
A Three-Dimensional Microporous Metal–Metalloporphyrin Framework
Inorganic Chemistry
Document Type
Article
Disciplines
Publication Version
Published Version
Publication Date
1-1-2015
DOI
10.1021/ic502116k
Abstract
A new porphyrin-based microporous MOF, {Mn(II)0.5[Mn(II)4Cl(Mn(III)Cl-ttzpp)2(H2O)4]}·(DEF)20·(CH3OH)18·(H2O)12 (UTSA-57), has been constructed from {5,10,15,20-tetrakis[4-(2,3,4,5-tetrazolyl)phenyl]porphyrinato} manganese(III) chloride as the metalloligand. The MOF adopts the rare scu topology with one-dimensional square nanotube-like channels of about 20 Å. UTSA-57a exhibits permanent porosity and displays moderately high performance for C2H2/CH4 separation at room temperature.
Copyright Owner
American Chemical Society
Copyright Date
2015
Language
en
File Format
application/pdf
Citation Information
Zhiyong Guo, Dan Yan, Hailong Wang, Daniel Tesfagaber, et al.. "A Three-Dimensional Microporous Metal–Metalloporphyrin Framework" Inorganic Chemistry Vol. 54 Iss. 1 (2015) p. 200 - 204 Available at: http://works.bepress.com/wenyu_huang/4/
Reprinted (adapted) with permission from Inorg. Chem., 2015, 54 (1), pp 200–204. Copyright 2015 American Chemical Society