Linear Dichroism in Resonant Inelastic X-Ray Scattering to Molecular Spin-Orbit StatesPhysical Review Letters
AbstractPolarization-dependent resonant inelastic x-ray scattering (RIXS) is shown to be a new probe of molecular-field effects on the electronic structure of isolated molecules. A combined experimental and theoretical analysis explains the linear dichroism observed in Cl 2p RIXS following Cl 1s excitation in HCl and CF3Cl as due to molecular-field effects, including singlet-triplet exchange, indicating polarized-RIXS provides a direct probe of spin-orbit-state populations applicable to any molecule.
PermissionsCopyright American Physical Society, used with permission
Citation InformationRenaud Guillemin, Stephane Carniato, Wayne C. Stolte, Loic Journel, et al.. "Linear Dichroism in Resonant Inelastic X-Ray Scattering to Molecular Spin-Orbit States" Physical Review Letters Vol. 101 Iss. 133003 (2008) p. 4
Available at: http://works.bepress.com/wayne_stolte/8/