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Article
Ionic fragmentation of deep core-level (Cl 1s) excited chloroform molecule
Journal of Electron Spectroscopy and Related Phenomena
  • A. F. Lago, Universidade Federal do Rio de Janeiro
  • A.C. F. Santos, Universidade Federal do Rio de Janeiro
  • Alfred S. Schlachter, Lawrence Berkeley National Laboratory
  • Wayne C. Stolte, University of Nevada, Las Vegas
  • G.G. B. de Souza, Universidade Federal do Rio de Janeiro
Document Type
Article
Publication Date
6-1-2005
Abstract

The ionic fragmentation of the chloroform (CHCl3) molecule has been studied along the Cl1s edge, using synchrotron radiation and a magnetic mass spectrometer. The following cations were observed: Cl+, Cl2+, CCl+, CCl2+, CHCl+, Cl3+, H+ and C+. While all ions are seen to be formed at the intense resonance which dominates the photoabsorption spectrum below the chlorine 1s edge (taken to occur at 2828.6 eV), the probability of observation of the CHCl+, C+ and Cl3+ cations is seen to significantly decrease above the ionization edge.

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Citation Information
A. F. Lago, A.C. F. Santos, Alfred S. Schlachter, Wayne C. Stolte, et al.. "Ionic fragmentation of deep core-level (Cl 1s) excited chloroform molecule" Journal of Electron Spectroscopy and Related Phenomena Vol. 144-147 (2005) p. 161 - 163
Available at: http://works.bepress.com/wayne_stolte/56/