Resonant inelastic x-ray scattering of methyl chloride at the chlorine K edgeJournal of Chemical Physics
AbstractWe present a combined experimental and theoretical study of isolated CH3Cl molecules using resonant inelastic x-ray scattering (RIXS). The high-resolution spectra allow extraction of information about nuclear dynamics in the core-excited molecule. Polarization-resolved RIXS spectra exhibit linear dichroism in the spin-orbit intensities, a result interpreted as due to chemical environment and singlet-triplet exchange in the molecular core levels. From analysis of the polarization-resolved data, Cl 2px, y and 2pz electronic populations can be determined.
Citation InformationL. El Khoury, Loic Journel, Renaud Guillemin, Stephane Carniato, et al.. "Resonant inelastic x-ray scattering of methyl chloride at the chlorine K edge" Journal of Chemical Physics (2012) p. 1 - 7
Available at: http://works.bepress.com/wayne_stolte/51/