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Article
Fragmentation of methyl chloride studied by partial positive and negative ion yield spectroscopy
Journal of chemical physics
  • D. Ceolin, Uppsala University
  • Maria Novella Piancastelli, Uppsala University
  • Renaud Guillemin, CNRS, Laboratoire de Chimie Physique-Matière et Rayonnement
  • Wayne C. Stolte, University of Nevada, Las Vegas
  • S-W Yu, Lawrence Berkeley National Laboratory
  • Oliver Hemmers, University of Nevada, Las Vegas
  • Dennis W. Lindle, University of Nevada, Las Vegas
Document Type
Article
Publication Date
2-1-2007
Publisher
American Institute of Physics
Abstract
The authors present partial-ion-yield experiments on the methyl chloride molecule excited in the vicinity of the Cl2p and C1s inner shells. A large number of fragments, cations produced by dissociation or recombination processes, as well as anionic species, have been detected. Although the spectra exhibit different intensity distributions depending on the core-excited atom, general observations include strong site-selective fragmentation along the C–Cl bond axis and a strong intensity dependence of transitions involving Rydberg series on fragment size.
Keywords
  • Chemical bonds,
  • Collisions (Nuclear physics),
  • Ion recombination,
  • Molecule-photon collisions,
  • Organic compounds,
  • Photodissociation,
  • Rydberg states
Language
English
Permissions
Copyright (2007) American Institute of Physics. This article may be downloaded for personal use only. Any other use requires prior permission of the author and the American Institute of Physics.
Identifier
DOI: http://dx.doi.org/10.1063/1.2464093
Citation Information
D. Ceolin, Maria Novella Piancastelli, Renaud Guillemin, Wayne C. Stolte, et al.. "Fragmentation of methyl chloride studied by partial positive and negative ion yield spectroscopy" Journal of chemical physics Vol. 126 Iss. 8 (2007) p. 084309-1 - 084309-8
Available at: http://works.bepress.com/wayne_stolte/39/