Sulfur K-edge photo-fragmentation of ethylene sulfideJournal of Chemical Physics
AbstractWe have investigated the photofragmentation properties of the three-membered ring heterocyclic molecule ethylene sulfide or thiirane, C2H4S, by time-of-flight mass spectroscopy. Positive ions have been collected as a function of photon energy around the S K ionization threshold. Branching ratios were derived for all detected ions, which are informative of the decay dynamics and photofragmentation patterns of the core-excited species. We present a new assignment of the spectral features around the S K-edge.
- Atomic orbitals,
- Electron configuration,
- Mass spectroscopy,
- Organosulfur compounds
PermissionsCopyright American Institute of Physics, used with permission
Publisher CitationStolte, Wayne C., and G. Öhrwall. "Sulfur K-edge photofragmentation of ethylene sulfide." The Journal of chemical physics 133 (2010): 014306.
Citation InformationWayne C. Stolte and Gunnar Ohrwall. "Sulfur K-edge photo-fragmentation of ethylene sulfide" Journal of Chemical Physics Vol. 133 Iss. 014306 (2010) p. 014306-1 - 014306-6
Available at: http://works.bepress.com/wayne_stolte/36/