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Article
Photofragmentation of BF3 upon B and F K-shell excitation by partial-ion-yield spectroscopy
Journal of Physics B: Atomic, Molecular and Optical Physics
  • Renaud Guillemin, CNRS, Laboratoire de Chimie Physique-Matière et Rayonnement
  • Wayne C. Stolte, University of Nevada, Las Vegas
  • Maria Novella Piancastelli, Uppsala University
  • Dennis W. Lindle, University of Nevada, Las Vegas
Document Type
Article
Publication Date
10-1-2010
Abstract

The fragmentation of core-excited BF3 has been studied by means of partial cation and anion yield measurements around the B and F K edges. All detectable ionic fragments are reported, and differences among the fragments are discussed. The observations confirm earlier findings on the dynamics of molecular fragmentation studied by partial ion yields, notably on the influence of Rydberg excitations on fragmentation, the behaviour of anion production near threshold, and the importance of intramolecular rearrangement in the formation of F+2 ions.

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Citation Information
Renaud Guillemin, Wayne C. Stolte, Maria Novella Piancastelli and Dennis W. Lindle. "Photofragmentation of BF3 upon B and F K-shell excitation by partial-ion-yield spectroscopy" Journal of Physics B: Atomic, Molecular and Optical Physics Vol. 43 Iss. 215205 (2010) p. 1 - 7
Available at: http://works.bepress.com/wayne_stolte/15/