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Contribution to Book
Numerical Investigation of Water Transport in the PEMFC Components
Proceedings of the Electrochemical Society Transactions (2006)
  • Vladimir Gurau, Georgia Southern University
  • J. Adin Mann, Case Western Reserve University
  • Tom Zawodzinski, Case Western Reserve University
Abstract
There are two competing mechanisms of water transfer between the ionomer-phase distributed in the catalyst layer and the catalyst layer pores; these are: (i) sorption/desorption and (ii) water dragged by the protons engaged in the electrochemical reaction (the secondary current). The level at which water accumulates in GDLs is determined by the saturation equilibrium at the GDL-channel interface. The level at which water accumulates in the catalyst layer is determined by the GDL permeability and the saturation equilibrium at the GDL-catalyst layer interface. In the cathode flow domain mass is overall produced by (i) mass of protons crossing the double-layer and (ii) mass of water transferred between the ionomer-phase distributed in the catalyst layer and the catalyst layer pores; for this reason the homogeneous multi-phase models based on the two-phase mixture model are inadequate to describe two-phase phenomena in PEMFCs. We propose a multi-phase, multi-fluid model that captures these phenomena.
Keywords
  • Component,
  • Stack and system modeling,
  • Numerical investigation,
  • Water transport,
  • PEMFC components
Disciplines
Publication Date
October 29, 2006
Publisher
Electrochemical Society
DOI
10.1149/1.2356229
Citation Information
Vladimir Gurau, J. Adin Mann and Tom Zawodzinski. "Numerical Investigation of Water Transport in the PEMFC Components" Cancun, MexicoProceedings of the Electrochemical Society Transactions Vol. 3 (2006) p. 1095 - 1104
Available at: http://works.bepress.com/vladimir-gurau/17/