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Adsorption Behavior and Reduction of Copper (II) Acetate on the Surface of Detonation Nanodiamond with Well Defined Surface Chemistry
Carbon
  • Kostiantyn Turcheniuk
  • Vadym Mochalin, Missouri University of Science and Technology
Abstract

We report a novel wet chemistry route to metal coated nanodiamond particles. The technique includes adsorption of copper (II) acetate followed by reduction with hydrazine. To understand factors influencing the adsorption of the copper salt, nanodiamonds with different and well defined chemistries have been synthesized. The interaction of copper ions with NDs was studied by means of adsorption isotherms revealing different behavior depending on nanodiamond surface chemistry. Reduction of copper ions adsorbed on nanodiamond yields nanodiamond particles encapsulated into copper shells (ND@Cu). Using this technique, we can achieve up to 7.5 wt% of metallic copper on the nanodiamond surface, which is 3 times higher than reported so far. Synthesized copper coated nanodiamond particles will be used as a convenient nanofiller to reinforce copper and other metals with nanodiamond.

Department(s)
Chemistry
Research Center/Lab(s)
Center for High Performance Computing Research
Keywords and Phrases
  • Adsorption,
  • Copper,
  • Metal Coatings,
  • Metal Ions,
  • Surface Chemistry,
  • Adsorption Behavior,
  • Copper Salt,
  • Copper Shell,
  • Detonation Nanodiamond,
  • Metal-Coated,
  • Metallic Copper,
  • Nano-Diamond Particles,
  • Wet Chemistry Routes,
  • Nanodiamonds
Document Type
Article - Journal
Document Version
Citation
File Type
text
Language(s)
English
Rights
© 2016 Elsevier Ltd, All rights reserved.
Publication Date
11-1-2016
Publication Date
01 Nov 2016
Citation Information
Kostiantyn Turcheniuk and Vadym Mochalin. "Adsorption Behavior and Reduction of Copper (II) Acetate on the Surface of Detonation Nanodiamond with Well Defined Surface Chemistry" Carbon Vol. 109 (2016) p. 98 - 105 ISSN: 0008-6223
Available at: http://works.bepress.com/vadym-mochalin/63/