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Article
Anomalous phonon behavior in the high-temperature shape-memory alloy Ti50Pd50−xCrx
Physical Review B
  • S. M. Shapiro, Brookhaven National Laboratory
  • Guangyong Xu, Brookhaven National Laboratory
  • Deborah L. Schlagel, Iowa State University
  • Thomas A. Lograsso, Iowa State University
  • R. Erwin, National Institute of Standards and Technology
Document Type
Article
Publication Date
8-17-2007
DOI
10.1103/PhysRevB.76.054305
Abstract

Ti50Pd50−xCrx is a high-temperature shape-memory alloy with a martensitic transformation temperature strongly dependent on the Cr composition. Prior to the transformation, a premartensitic phase is present with an incommensurate modulated cubic lattice with wave vector of q0=(0.22,0.22,0). The temperature dependence of the diffuse scattering in the cubic phase is measured as a function temperature for x=6.5, 8.5, and 10 at. %. The lattice dynamics has been studied and reveals anomalous temperature andq dependences of the [110]-TA2 transverse phonon branch. The phonon linewidth is broad over the entire Brillouin zone and increases with decreasing temperature, contrary to the behavior expected for anharmonicity. No anomaly is observed at q0. The results are compared with first principles calculation of the phonon structure.

Comments

This article is from Physical Review B 76 (2007): 054305, doi:10.1103/PhysRevB.76.054305.

Copyright Owner
American Physical Society
Language
en
File Format
application/pdf
Citation Information
S. M. Shapiro, Guangyong Xu, Deborah L. Schlagel, Thomas A. Lograsso, et al.. "Anomalous phonon behavior in the high-temperature shape-memory alloy Ti50Pd50−xCrx" Physical Review B Vol. 76 Iss. 5 (2007) p. 054305
Available at: http://works.bepress.com/thomas_lograsso/57/