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Article
Molecular lifetimes in the presence of periodically roughened metallic surfaces
Physical Review B
  • P.T. Leung, Portland State University
  • Z. C. Wu
  • Daniel A. Jelski
  • Thomas F. George
Document Type
Article
Publication Date
7-1-1987
Subjects
  • Molecular structure,
  • Metals -- Surfaces,
  • Boundary value problems
Disciplines
Abstract

The lifetimes of molecules located close to a sinusoidal grating surface are studied within a classical phenomenological model. The contribution of surface roughness to the molecular decay rate is attributed to the discrepancy between the experiments of Rossetti and Brus and the theory of Chance, Prock, and Silbey. It is found that surface roughness can either enhance or diminish the flat-surface value for the decay rate depending on the emitting frequency, molecule-surface distance, and the molecular orientation.

Description

This is the publisher's final pdf. Article appears in Physical Review B (http://prb.aps.org/) and is copyrighted by APS Journals (http://publish.aps.org/).

DOI
10.1103/PhysRevB.36.1475
Persistent Identifier
http://archives.pdx.edu/ds/psu/7696
Citation Information
Leung, P. T., Wu, Z. C., Jelski, D. A., & George, T. F. (1987). Molecular lifetimes in the presence of periodically roughened metallic surfaces. Physical Review B (Condensed Matter), 36(3), 1475-1479.