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Article
Rapid and ordered carbonylation and oxygenation of a cobalt(II) methyl
Ames Laboratory Accepted Manuscripts
  • Regina R. Reinig, Iowa State University and Ames Laboratory
  • Ellie L. Fought, Iowa State University and Ames Laboratory
  • Arkady Ellern, Iowa State University
  • Theresa Lynn Windus, Iowa State University and Ames Laboratory
  • Aaron D. Sadow, Iowa State University and Ames Laboratory
Publication Date
1-1-2017
Department
Ames Laboratory; Chemistry
Report Number
IS-J 9445
DOI
10.1039/C7CC06339C
Journal Title
Chemical Communications
Abstract

The oxidative carbonylation of ToMCoMe (1; ToM = tris(4,4-dimethyl-2-oxazolinyl)phenylborate) involves its rapid, reversible reaction with CO to form ToMCo{C(O)Me}CO (2) followed by rapid reaction with O2 yielding ToMCoOAc (3), in contrast to the slow direct carboxylation of ToMCoMe by CO2.

Language
en
Publisher
Iowa State University Digital Repository, Ames IA (United States)
Disciplines
Citation Information
Regina R. Reinig, Ellie L. Fought, Arkady Ellern, Theresa Lynn Windus, et al.. "Rapid and ordered carbonylation and oxygenation of a cobalt(II) methyl" Vol. 53 (2017) p. 11020 - 11023
Available at: http://works.bepress.com/theresa-windus/27/