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Selected Works of Takele Seda
Article
Ligand-based reduction of CO2 and release of CO on iron(II).
Inorganic Chemistry (2012)
  • Zachary Thammavongsy, Western Washington University
  • Takele Seda, Western Washington University
  • Lev N. Zakharov, University of Oregon
  • Werner Kaminsky, University of Washington
  • John D. Gilbertson, Western Washington University
Link
Abstract
A synthetic cycle for the CO2-to-CO conversion (with subsequent release of CO) based on iron(II), a redox-active pydridinediimine ligand (PDI), and an O-atom acceptor is reported. This conversion is a passive-type ligand-based reduction, where the electrons for the CO2 conversion are supplied by the reduced PDI ligand and the ferrous state of the iron is conserved.
Keywords
  • Carbon dioxide,
  • Carbon dioxide mitigation
Disciplines
Publication Date
September 3, 2012
DOI
10.1021/ic3015404
Publisher Statement
© 2012 American Chemical Society
Citation Information
Ligand-Based Reduction of CO2 and Release of CO on Iron(II) Zachary Thammavongsy, Takele Seda, Lev N. Zakharov, Werner Kaminsky, and John D. Gilbertson Inorganic Chemistry 2012 51 (17), 9168-9170 DOI: 10.1021/ic3015404