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Selected Works of Takele Seda
Article
Nitrite reduction by a pyridinediimine complex with a proton-responsive secondary coordination sphere
Chemical Communications (2016)
  • Yubin M. Kwon, Western Washington University
  • Mayra Delgado, Western Washington University
  • Lev N. Zakharov, University of Oregon
  • Takele Seda, Western Washington University
  • John D. Gilbertson, Western Washington University
Link
Abstract
The proton-responsive pyridinediimine ligand, DEAPDI (where DEAPDI = [(2,6-iPrC6H3)(NCMe)(N(Et)2C2H4)(NCMe)C5H3N]) was utilized for the reduction of NO2− to NO. Nitrite reduction is facilitated by the protonated secondary coordination sphere coupled with the ligand-based redox-active sites of [Fe(HDEAPDI)(CO)2]+ and results in the formation of the {Fe(NO)2}9 DNIC, [Fe(DEAPDI)(NO)2]+.
Keywords
  • Redox reactions,
  • Pyridinediimine ligand,
  • Nitrite reduction
Disciplines
Publication Date
January 1, 2016
DOI
10.1039/C6CC05962G
Publisher Statement
This journal is © The Royal Society of Chemistry 2016
Citation Information
Yubin M. Kwon, Mayra Delgado, Lev N. Zakharov, Takele Seda, et al.. "Nitrite reduction by a pyridinediimine complex with a proton-responsive secondary coordination sphere" Chemical Communications Vol. 52 Iss. 73 (2016) p. 11016 - 11019
Available at: http://works.bepress.com/takele-seda/18/