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Selected Works of Takele Seda
Article
Pyridinediimine Iron Complexes with Pendant Redox-Inactive Metals Located in the Secondary Coordination Sphere.
Inorganic Chemistry (2016)
  • Mayra Delgado, Western Washington University
  • Joshua M. Ziegler, Western Washington University
  • Takele Seda, Western Washington University
  • Lev N. Zakharov
  • John D. Gilbertson, Western Washington University
Link
Abstract
A series of pyridinediimine (PDI) iron complexes that contain a pendant 15-crown-5 located in the secondary coordination sphere were synthesized and characterized. The complex Fe(15c5PDI)(CO)2 (2) was shown in both the solid state and solution to encapsulate redox-inactive metal ions. Modest shifts in the reduction potential of the metal–ligand scaffold were observed upon encapsulation of either Na+ or Li+.
Keywords
  • pyridinediimine (PDI) complexes,
  • Pyridinediimine Iron Complexes,
  • Lewis acids
Disciplines
Publication Date
January 19, 2016
DOI
10.1021/acs.inorgchem.5b02544
Publisher Statement
Copyright 2016 American Chemical Society
Citation Information
Pyridinediimine Iron Complexes with Pendant Redox-Inactive Metals Located in the Secondary Coordination Sphere. Mayra Delgado, Joshua M. Ziegler, Takele Seda, Lev N. Zakharov, and John D. Gilbertson. Inorganic Chemistry 2016 55 (2), 555-557 DOI: 10.1021/acs.inorgchem.5b02544