Article
Effect of Magnesium Bond on the Competition Between Hydrogen Bond and Halogen Bond and the Induction of Proton and Halogen Transfer
ChemPhysChem
Document Type
Article
Publication Date
4-25-2018
Publisher
Wiley-VCH Verlag GmbH & Co. KGaA
Disciplines
Abstract
HOX (X=Cl, Br, I, and At) can engage in either a H‐bond (HB) or halogen bond (XB) with a base‐like HCN, NH3, and imidazole. Although the former is energetically preferred for X=Cl and Br, it is the XB that is more stable for At, with I showing little preference. MgY2 forms a Mg‐bond with the O atom of HOX, which grows stronger in the order X=Cl
Citation Information
Hui‐Li, X., Li Qing‐Zhong, Scheiner, S. I. (2018). Effect of Magnesium Bond on the Competition Between Hydrogen and Halogen Bonds and the Induction of Proton and Halogen Transfer. ChemPhysChem, 19(12), 1456-1464. https://onlinelibrary.wiley.com/doi/abs/10.1002/cphc.201800102
This is the peer reviewed version of the following article: Hui‐Li, X., Li Qing‐Zhong, Scheiner, S. I. (2018). Effect of Magnesium Bond on the Competition Between Hydrogen and Halogen Bonds and the Induction of Proton and Halogen Transfer. ChemPhysChem, 19(12), 1456-1464. https://onlinelibrary.wiley.com/doi/abs/10.1002/cphc.201800102, which has been published in final form at https://doi.org/10.1002/cphc.201800102. This article may be used for non-commercial purposes in accordance with Wiley Terms and Conditions for Use of Self-Archived Versions.