The effects of carbon chains placed on the electron-accepting P atom of a P⋯N bond are examined via ab initio calculations. Saturated alkyl groups have a mild weakening effect, regardless of chain length. In contrast, incorporation of double bonds into the chain strengthens the interaction, Ctriple bond; length of mdashC triple bonds even more so. These effects are only slightly enhanced by additional conjugated double bonds or an aromatic ring. Placing F atoms onto the carbon chains strengthens the P⋯N bond, but only by a small amount, which wanes as the F atom is displaced further from the P along the chain.
Effects of Carbon Chain Substituent on the P∙∙∙N Noncovalent BondChem. Phys. Lett.
Citation InformationEffects of Carbon Chain Substituent on the P∙∙∙N Noncovalent Bond U. Adhikari, S. Scheiner Chem. Phys. Lett. 2012 536 30-33