Article
Ab Initio Investigations of the Hydrolysis of the Carbamate Bond
Journal of Molecular Structure: THEOCHEM
(1990)
Abstract
The energies for model gas-phase decomposition and hydrolysis reactions ofcarbamic acid and methyl carbamate have been calculated at various levels of theory. The calculations indicate that esterification accelerates cleavage of the carbamate bond.
Keywords
- Ab,
- initio,
- investigations,
- hydrolysis,
- carbamate,
- bond
Disciplines
Publication Date
January 1, 1990
Citation Information
Ab Initio Investigations of the Hydrolysis of the Carbamate Bond
M. Remko and S. Scheiner
J. Mol. Struct., (Theochem) 1990 204, 331-335.