Article
Synthesis and Crystal Structure of Barium Thioborate Ba7(BS3)4S
Inorganic Chemistry
Document Type
Article
Disciplines
Publication Date
5-3-2004
DOI
10.1021/ic035454m
Abstract
The thioborate phase Ba7(BS3)4S crystallizes in the monoclinic space group C2/c (No. 15) with a = 10.1750(15) Å, b = 23.970(4) Å, c = 10.1692(15) Å, β = 90.095(2)°, and Z = 4. The structure consists of isolated trigonal planar (BS3)3- anions, and isolated S2- anions and Ba2+ cations. The vibrational modes of the isolated (BS3)3- units were measured from Raman scattering and IR absorption spectra, and the frequencies agree very well with those found for similar orthothioborate phases.
Copyright Owner
American Chemical Society
Copyright Date
2004
Language
en
File Format
application/pdf
Citation Information
Youngsik Kim and Steve W. Martin. "Synthesis and Crystal Structure of Barium Thioborate Ba7(BS3)4S" Inorganic Chemistry Vol. 43 Iss. 9 (2004) p. 2773 - 2775 Available at: http://works.bepress.com/steve_martin/36/
Reprinted with permission from Inorganic Chemistry 43 (2004): 2773–2775, doi:10.1021/ic035454m. Copyright 2004 American Chemistry