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Faculty Selected Works of Stephen Holmes
Article
Reversible Thermally and Photoinduced Electron Transfer in a Cyano‐Bridged {Fe2Co2} Square Complex
Angewandte Chemie (2010)
  • Yuanzhu Zhang, University of Missouri–St. Louis
  • Dongfeng Li, University of Bordeaux
  • Dongfeng Li, Central China Normal University
  • Dongfeng Li, Centre national de la recherche scientifique
  • Rodolphe Clérac, University of Bordeaux
  • Rodolphe Clérac, Centre national de la recherche scientifique
  • Marguerite Kalisz, University of Bordeaux
  • Marguerite Kalisz, Centre national de la recherche scientifique
  • Corine Mathonière, University of Bordeaux
  • Stephen M. Holmes, University of Missouri–St. Louis
Link
Abstract
Flip to be square: Structural, spectroscopic, magnetic, and photomagnetic studies conclusively demonstrate that a tetranuclear cyanometalate {Fe2Co2} complex undergoes reversible thermally and light‐induced changes in its optical and magnetic properties. This bistability is induced by an intramolecular electron transfer, as observed in three‐dimensional Co/Fe Prussian blue compounds (see picture).
Disciplines
Publication Date
April 21, 2010
DOI
10.1002/anie.201000765
Citation Information
Yuanzhu Zhang, Dongfeng Li, Dongfeng Li, Dongfeng Li, et al.. "Reversible Thermally and Photoinduced Electron Transfer in a Cyano‐Bridged {Fe2Co2} Square Complex" Angewandte Chemie Vol. 49 Iss. 22 (2010) p. 3752 - 3756
Available at: http://works.bepress.com/stephen-holmes/8/