"Syntheses, Structures, and Magnetic Characterizatoin of Dicyanometalate(II) Building Blocks: [NEt4][(Tp*)M^II(CN)2] [M^II = Cr, Co, Ni; Tp* = Hydridotris(3,5-dimethylpyrazol-1-yl)borate]" by Stephen Holmes

Faculty Selected Works of Stephen Holmes

Article

Syntheses, Structures, and Magnetic Characterizatoin of Dicyanometalate(II) Building Blocks: [NEt4][(Tp*)M^II(CN)2] [M^II = Cr, Co, Ni; Tp* = Hydridotris(3,5-dimethylpyrazol-1-yl)borate]

Chemical Communications (2006)

Stephen Holmes, University of Missouri-St. Louis
Dongfeng Li, University of Kentucky
Chad Ruschmann, University of Kentucky
Rodolphe Clérac, Centre de Recherche Paul Pascal

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Abstract

The syntheses and structures of three dicyanometalate(II) complexes, [NEt4][(Tp*)MII(CN)2]·nMeCN·½Et2O (MII = Cr, 1, n = ½; Co, 2, n = 1; Ni, 3, n = 1) are described; magnetic studies indicate that 3 is diamagnetic while 1 and 2 are paramagnetic high- and low-spin S = 2 and ½ complexes, respectively.

Disciplines

Physical Sciences and Mathematics

Publication Date

2006

Citation Information

Stephen Holmes, Dongfeng Li, Chad Ruschmann and Rodolphe Clérac. "Syntheses, Structures, and Magnetic Characterizatoin of Dicyanometalate(II) Building Blocks: [NEt4][(Tp*)M^II(CN)2] [M^II = Cr, Co, Ni; Tp* = Hydridotris(3,5-dimethylpyrazol-1-yl)borate]" Chemical Communications Iss. 38 (2006)
Available at: http://works.bepress.com/stephen-holmes/32/