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Faculty Selected Works of Stephen Holmes
Article
An S = 2 Cyanide-bridged Trinuclear Fe^III2Ni^II Single-molecule Magnet
Inorganic Chemistry (2006)
  • Stephen Holmes, University of Missouri-St. Louis
  • Dongfeng Li, University of Kentucky
  • Rodolphe Clérac, Centre de Recherche Paul Pascal
  • Sean Parkin, University of Kentucky
  • Guangbin Wang, Virginia Polytechnic Institute and State University
  • Gordon T. Yee, Virginia Tech
Link
Abstract
Treatment of [NEt4][(pzTp)FeIII(CN)3] (1) with NiII(OTf)2 (OTf = trifluoromethanesulfonate) and 1,5,8,12-tetraazododecane (L) or 2,2‘-bipyridine (bipy) affords two cyanide-bridged trinuclear FeIII2NiII complexes of {[(pzTp)FeIII(CN)3]2[NiII(L)]}·1/2MeOH (2) and {[(pzTp)FeIII(CN)3]2[NiII(bipy)2]}·2H2O (3) stoichiometry. Complex 3 exhibits slow relaxation of the magnetization above 2 K.
Disciplines
Publication Date
2006
DOI
10.1021/ic060379b
Citation Information
Stephen Holmes, Dongfeng Li, Rodolphe Clérac, Sean Parkin, et al.. "An S = 2 Cyanide-bridged Trinuclear Fe^III2Ni^II Single-molecule Magnet" Inorganic Chemistry Vol. 45 Iss. 14 (2006) p. 5251 - 5253
Available at: http://works.bepress.com/stephen-holmes/29/