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Faculty Selected Works of Stephen Holmes
Article
Synthesis and Spectroscopic and Magnetic Characterization of Tris(3,5-dimenthylpyrazol-1-yl)borate Iron Tricyanide Building Blocks, a Cluster, and a One-dimensional Chain of Squares
Inorganic Chemistry (2006)
  • Stephen Holmes, University of Missouri-St. Louis
  • Dongfeng Li, University of Kentucky
  • Sean Parkin, University of Kentucky
  • Guangbin Wang, Virginia Polytechnic Institute and State University
  • Gordon T. Yee, Virginia Tech
Link
Abstract
The synthesis and spectroscopic and magnetic characterization of several hydridotris(3,5-dimethylpyrazol-1yl)borate iron(II,III) tricyanide complexes, a one-dimensional network, and a rectangular cluster are described. Treatment of [NEt4][(Tp*)FeIII(CN)3] with manganese(II) tosylate in DMF affords 1-D lattices, while triflate salts afford rectangular clusters. Magnetic studies indicate that the [(Tp*)Fe(CN)3]- centers are highly anisotropic (g = 2.92) and couple antiferromagnetically to the MnII centers present.
Disciplines
Publication Date
2006
DOI
10.1021/ic051044h
Citation Information
Stephen Holmes, Dongfeng Li, Sean Parkin, Guangbin Wang, et al.. "Synthesis and Spectroscopic and Magnetic Characterization of Tris(3,5-dimenthylpyrazol-1-yl)borate Iron Tricyanide Building Blocks, a Cluster, and a One-dimensional Chain of Squares" Inorganic Chemistry Vol. 45 Iss. 5 (2006) p. 1951 - 1959
Available at: http://works.bepress.com/stephen-holmes/26/