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Facile synthesis of a interleaved expanded graphite-embedded sulphur nanocomposite as cathode of Li-S batteries with excellent lithium storage performance
Faculty of Engineering - Papers (Archive)
  • Yun-Xiao Wang, University of Wollongong
  • Ling Huang, State Key Laboratory Of Physical Chemistry Of Solid Surfaces
  • Li-Chao Sun, State Key Laboratory Of Physical Chemistry Of Solid Surfaces
  • Su-Yuan Xie, State Key Laboratory Of Physical Chemistry Of Solid Surfaces
  • Gui-Liang Xu, State Key Laboratory Of Physical Chemistry Of Solid Surfaces
  • Shu-Ru Chen, State Key Laboratory Of Physical Chemistry Of Solid Surfaces
  • Yue-Feng Xu, State Key Laboratory Of Physical Chemistry Of Solid Surfaces
  • Jun-Tiao Li, Xiamen University
  • Shulei Chou, University of Wollongong
  • S. X. Dou, University of Wollongong
  • Shi-Gang Sun, State Key Laboratory Of Physical Chemistry Of Solid Surfaces
RIS ID
52553
Publication Date
1-1-2012
Publication Details

Wang, Y., Huang, L., Sun, L., Xie, S., Xu, G., Chen, S., Xu, Y., Li, J., Chou, S., Dou, S. & Sun, S. (2012). Facile synthesis of a interleaved expanded graphite-embedded sulphur nanocomposite as cathode of Li-S batteries with excellent lithium storage performance. Journal of Materials Chemistry, 22 (11), 4744-4750.

Abstract

This paper reports the facile synthesis of a unique interleaved expanded graphite-embedded sulphur nanocomposite (S-EG) by melt-diffusion strategy. The SEM images of the S-EG materials indicate the nanocomposites consist of nanosheets with a layer-by-layer structure. Electrochemical tests reveal that the nanocomposite with a sulphur content of 60% (0.6S-EG) can deliver the highest discharge capacity of 1210.4 mAh g−1 at a charge–discharge rate of 280 mA g−1 in the first cycle, the discharge capacity of the 0.6S-EG remains as high as 957.9 mAh g−1 after 50 cycles of charge–discharge. Furthermore, at a much higher charge–discharge rate of 28 A g−1, the 0.6S-EG cathode can still deliver a high reversible capacity of 337.5 mAh g−1. The high sulphur utilization, excellent rate capability and reduced over-discharge phenomenon of the 0.6S-EG material are exclusively attributed to the particular microstructure and composition of the cathode.

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Citation Information
Yun-Xiao Wang, Ling Huang, Li-Chao Sun, Su-Yuan Xie, et al.. "Facile synthesis of a interleaved expanded graphite-embedded sulphur nanocomposite as cathode of Li-S batteries with excellent lithium storage performance" (2012) p. 4744 - 4750
Available at: http://works.bepress.com/shulei/39/