Article
Microwave-Assisted Oxidative Coupling of Amines to Imines on Solid Acid Catalysts
Tetrahedron Letters
(2007)
Abstract
A K-10 montmorillonite catalyzed microwave-assisted oxidative coupling of amines is described. Substituted benzylamines readily undergo self-coupling reactions to produce benzylidene–benzylamines, while aliphatic amines and anilines cannot form self-coupled products. A mixture of a benzylamine and an aniline or aliphatic amine, respectively, effectively, and selectively produces mixed imines, such as benzylidene–anilines and benzylidene–alkylamines.
Keywords
- Microwave-assisted,
- Oxidative coupling,
- Amines,
- Imines,
- Benzylamines,
- Solid acid catalysts
Disciplines
Publication Date
July 16, 2007
DOI
0.1016/j.tetlet.2007.05.051
Citation Information
Shainaz M. Landge, Valentina Atanassova, Muralidhara Thimmaiah and Béla Török. "Microwave-Assisted Oxidative Coupling of Amines to Imines on Solid Acid Catalysts" Tetrahedron Letters Vol. 48 Iss. 29 (2007) p. 5161 - 5164 Available at: http://works.bepress.com/shainaz_landge/43/