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Presentation
Ion-pair States in Triplet Molecular Hydrogen
American Physical Society Division of Atomic, Molecular, and Optical Physics (2016)
  • Seth T Ashman, Providence College
  • W. Setzer, Wesleyan University
  • B. C Baker, Wesleyan University
  • T. J Morgan, Wesleyan University
Abstract
An experimental search is underway to observe the long range triplet ionic states H+ H− of molecular hydrogen. Resonantly enhanced multi photon ionization of the metastable c 3 ∏− u 2pπ state is used access to the R(1)nd1 n=21 Rydberg state that serves as an intermediate stepping stone state to probe the energy region above the ionization limit with a second tunable laser photon. The metastable state is prepared by electron capture of 6 keV H+ 2 ions in potassium in a molecular beam. Formation of the H+ H− triplet configuration involves triplet excited states of the H− ion, especially the 2p2 3P e state, the second bound state of H− predicted to exist with a lifetime long compared to typical auto ionization lifetimes but not yet observed experimentally. Details of the experiment and preliminary results to date will be presented at the conference.
Publication Date
May 26, 2016
Location
Providence, RI, US
Citation Information
Seth T Ashman, W. Setzer, B. C Baker and T. J Morgan. "Ion-pair States in Triplet Molecular Hydrogen" American Physical Society Division of Atomic, Molecular, and Optical Physics (2016)
Available at: http://works.bepress.com/seth-ashman/17/