Skip to main content
Article
NaK Bound-free and Bound-bound 43Σ+ a3Σ+ Emission
Journal of Molecular Spectroscopy (2011)
  • Seth T Ashman, Providence College
  • B. M McGeehan
  • C. M Wolfe
  • R. Steinhardt
  • M. L Monaco
  • J. Huennekens
  • A. P Hickman
Abstract
The relative transition dipole moment function M(R) for the 4 3Σ+ → a 3Σ+ electronic transition in the sodium–potassium molecule (NaK) has been determined by fitting experimental bound–free and bound–bound emission spectra. The fit is performed using a modified version of the BCONT computer program, which was originally developed by Le Roy. Spectra previously measured in this laboratory from low-lying ro vibrational levels of the 4 3Σ+ state and new spectra from high-lying levels are included in the fit. A slight adjustment to the inner, repulsive wall of the 4 3Σ+ potential leads to an improved form for that curve. The fitted M(R), when appropriately scaled, agrees very well with recent ab initio calculations of Magnier et al.
Disciplines
Publication Date
February, 2011
DOI
10.1016/j.jms.2010.11.004
Citation Information
Seth T Ashman, B. M McGeehan, C. M Wolfe, R. Steinhardt, et al.. "NaK Bound-free and Bound-bound 43Σ+ a3Σ+ Emission" Journal of Molecular Spectroscopy Vol. 265 Iss. 2 (2011) p. 74 - 80 ISSN: 0022-2852
Available at: http://works.bepress.com/seth-ashman/12/