Thermodynamic Equations for a Model Lithium-Ion CellElectrochimica Acta
AbstractFundamentals of classical thermodynamics of electrochemical systems have been employed to formulate mathematical equations for a model lithium-ion and lithium electrode concentration cell. Equations have been formulated to determine the energetic lithium interaction coefficients in the solid lithium-ion electrode phases and the salt mean activity coefficient in the electrolytic solution used in the model cell from the measured experimental data. In addition, a mathematical equation to predict the open-circuit voltage of the model cell for the case of differing electrolyte compositions in its porous electrodes has been developed.
CopyrightCopyright © 1999, Elsevier
Citation InformationSarwan S. Sandhu and Joseph P. Fellner. "Thermodynamic Equations for a Model Lithium-Ion Cell" Electrochimica Acta Vol. 45 Iss. 6 (1999)
Available at: http://works.bepress.com/sarwan_sandhu/8/