Article
Self‐Assembled Room Temperature Multiferroic BiFeO3‐LiFe5O8 Nanocomposites
Advanced Functional Materials
(2019)
Abstract
Multiferroic materials have driven significant research interest due to their promising technological potential. Developing new room‐temperature multiferroics and understanding their fundamental properties are important to reveal unanticipated physical phenomena and potential applications. Here, a new room temperature multiferroic nanocomposite comprised of an ordered ferrimagnetic spinel α‐LiFe5O8 (LFO) and a ferroelectric perovskite BiFeO3 (BFO) is presented. It is observed that lithium (Li)‐doping in BFO favors the formation of LFO spinel as a secondary phase during the synthesis of LixBi1−xFeO3 ceramics. Multimodal functional and chemical imaging methods are used to map the relationship between doping‐induced phase separation and local ferroic properties in both the BFO‐LFO composite ceramics and self‐assembled nanocomposite thin films. The energetics of phase separation in Li doped BFO and the formation of BFO‐LFO composites are supported by first principles calculations. These findings shed light on Li's role in the formation of a functionally important room temperature multiferroic and open a new approach in the synthesis of light element doped nanocomposites for future energy, sensing, and memory applications.
Disciplines
Publication Date
October 24, 2019
Citation Information
Yogesh K. Sharma, Radhe Agarwal, Liam Collins, Qiang Zheng, et al.. "Self‐Assembled Room Temperature Multiferroic BiFeO3‐LiFe5O8 Nanocomposites" Advanced Functional Materials (2019) ISSN: 1616-301X Available at: http://works.bepress.com/santosh-kc/2/