Article
Two manganese(II) coordination polymers driven by (iso)nicotinoyl-hydrazone blocks and pseudohalide ancillary ligands: syntheses, structural features, and magnetic properties
Journal of Coordination Chemistry
(2017)
Abstract
Two coordination polymers, [Mn2(μ-L1)2(μ-N3)2]n (1) and [Mn(μ-HL2)(SCN)2]n (2), were assembled in a single-pot from MnCl2·4H2O, HL1 (2-acetylpyridine isonicotinoylhydrazone) or HL2 (2-acetylpyridine nicotinoylhydrazone) and ancillary ligand sources (NaN3 or NH4NCS). The products were fully characterized, including by single-crystal X-ray diffraction, which revealed a 2-D metal–organic layer in 1 and a 1-D zigzag coordination chain in 2. Both 1 and 2 are constructed from six-coordinate Mn(II) nodes that adopt distorted octahedral (MnN5O) environments; the adjacent nodes are driven by the μ-L1 and μ-N3 linkers in 1 or μ-HL2 linkers in 2 to form different metal–organic networks. Their topological classification was performed, disclosing the hcb and 2C1topology in 1 and 2, respectively. Different weak non-covalent interactions promote dimensionality extension. Variable-temperature magnetic susceptibility measurements were carried out, revealing weak ferromagnetic and antiferromagnetic interactions in 1 and 2, respectively.
Disciplines
Publication Date
June 5, 2017
DOI
10.1080/00958972.2017.1334165
Citation Information
Ghodrat Mahmoudi, Habibar Chowdhury, Samuel E. Lofland, Barindra Kumar Ghosh, et al.. "Two manganese(II) coordination polymers driven by (iso)nicotinoyl-hydrazone blocks and pseudohalide ancillary ligands: syntheses, structural features, and magnetic properties" Journal of Coordination Chemistry Vol. 70 Iss. 12 (2017) p. 1973 - 1983 Available at: http://works.bepress.com/samuel-lofland/9/