The use of quaternion orthogonal designs (QODs) to describe point-to-point communication among dual-polarized antennas has the potential to provide higher rate orthogonal and quasi-orthogonal complex designs exploiting polarization diversity among space and time diversities. Furthermore, it is essential to have a space time block code (STBC) which offers a linear and decoupled decoder which quasi-orthogonal designs fail to attain. In this paper, we show how the realm of quaternions unexpectedly offers us a possible solution and codes obtained from quaternion designs mostly achieve both linear and decoupled decoders. This motivated us to perform an indispensable search for QODs such that the code rate is bounded below by 1/2 and does not sharply decrease as the number of transmit antennas increases. It is shown that three famous recursive techniques do not satisfy this criteria and their code rates decrease rather rapidly. Therefore, we propose another method of constructing quaternion designs suitable for any number of transmit antennas and verify that these attain linear and decoupled decoders with the system model based on quaternionic channel. It is shown that such designs outperform others in terms of transmit diversity, code rates and the optimality of the proposed decoder is validated through simulation results.