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Solubility of Gases in Liquids. 21. Solubility of He, Ne, Ar, Kr, N2, O2, CH4, CF4, and SF6 in 2,2,4-Trimethylpentane at T = 298.15 K
The Journal of Chemical Thermodynamics
  • Paul J. Hesse
  • Rubin Battino, Wright State University - Main Campus
  • Pirketta Scharlin
  • Emmerich Wilhelm
Document Type
Article
Publication Date
9-1-1999
Abstract

The Ostwald coefficients L2,1 of He, Ne, Ar, Kr, N2, O2 , CH4, CF4, and SF6 dissolved in 2,2,4-trimethylpentane (isooctane) have been measured at the temperature 298.15 K and the pressure 101325 Pa with a modified Ben-Naim/Baer-type apparatus. Subsequently, the L2,1 values are converted to Henry fugacities (Henry’s law constants) at the vapour pressure of the solvent, and mole fraction solubilities at a partial gas pressure p2 = 101325 Pa by using the thermodynamically rigorous methods previously given. This improved, medium-precision apparatus (the imprecision is about ± 0.5 per cent) combines easy handling with automated data retrieval and is totally mercury-free.

DOI
10.1006/jcht.1999.0529
Citation Information
Paul J. Hesse, Rubin Battino, Pirketta Scharlin and Emmerich Wilhelm. "Solubility of Gases in Liquids. 21. Solubility of He, Ne, Ar, Kr, N2, O2, CH4, CF4, and SF6 in 2,2,4-Trimethylpentane at T = 298.15 K" The Journal of Chemical Thermodynamics Vol. 31 Iss. 9 (1999) p. 1175 - 1181 ISSN: 00219614
Available at: http://works.bepress.com/rubin_battino/198/