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Article
Exploring the pH Dependence of Viologen Reduction by Alpha-Carbon Radicals Derived from HCy and Cys
Chemical Communications (Cambridge, England)
  • Dong Wang, Louisiana State University
  • William E. Crowe, Louisiana State University
  • Robert M. Strongin, Portland State University
  • Martha Sibrian-Vazquez, Portland State University
Document Type
Post-Print
Publication Date
1-1-2009
Subjects
  • Oxidation-reduction reaction,
  • Hydrogen-ion concentration,
  • Homocysteine
Disciplines
Abstract

The colorimetric reaction of homocysteine (HCy) with a series of viologen salts suggests a linear correlation between the mid-point reduction potential of Hcy-derived α-carbon radicals and pH.

Description

This is the author’s version of a work that was accepted for publication in Chemical Communications (Cambridge, England). Changes resulting from the publishing process, such as peer review, editing, corrections, structural formatting, and other quality control mechanisms may not be reflected in this document. Changes may have been made to this work since it was submitted for publication. A definitive version was subsequently published in Chemical Communications (Cambridge, England), 2009; (14):1876-8. doi:10.1039/b819746f

DOI
10.1021/es201981g
Persistent Identifier
http://archives.pdx.edu/ds/psu/11128
Citation Information
Dong Wang, William E. Crowe, Robert M. Strongin and Martha Sibrian-Vazquez. "Exploring the pH Dependence of Viologen Reduction by Alpha-Carbon Radicals Derived from HCy and Cys" Chemical Communications (Cambridge, England) (2009)
Available at: http://works.bepress.com/robert_strongin/9/