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Tetraethylammonium tri-mu-phenolato-bis[tricarbonylmanganate(I)]
ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE
  • Timothy J McNeese, Loyola University Maryland
  • Robert D Pike, College of William and Mary
Document Type
Article
Publication Date
8-1-2011
Disciplines
Abstract

The title compound, (C8H20N)[Mn-2(C6H5O)(3)(CO)(6)], was synthesized from [Mn(CO)(3)(CH3CN)(3)]BF4 and (C8H20N)-(OC6H5). The binuclear anion exhibits a pseudo-threefold symmetry and contains two six-coordinate Mn atoms. Each metal atom is coordinated by three facially oriented CO ligands and three doubly-bridging phenolate ligands. The average O-Mn-O bond angle is 74.9 (7)degrees in the Mn2O3 metal-phenolate dimeric core, yielding a distorted octahedron for each metal.

DOI
10.1107/S1600536811029266
Citation Information
Timothy J McNeese and Robert D Pike. "Tetraethylammonium tri-mu-phenolato-bis[tricarbonylmanganate(I)]" ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE Vol. 67 (2011)
Available at: http://works.bepress.com/robert-pike/151/