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Poly[mu-2-aminopyrazine-kappa N-2(1): N-4-mu-cyanido-copper(I)]: a three-dimensional network from laboratory powder diffraction data
ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS
  • Silvina Pagola, College of William and Mary
  • Robert D Pike, College of William and Mary
  • Kathryn deKrafft, College of William and Mary
  • Tristan A Tronic, College of William and Mary
Document Type
Article
Publication Date
3-1-2008
Disciplines
Abstract

In the title compound, [Cu(CN)(C4H5N3)](n) or [Cu(mu-CN)(mu-PyzNH(2))](n) (PyzNH(2) is 2-aminopyrazine), the Cu-I center is tetrahedrally coordinated by two cyanide and two PyzNH(2) ligands. The Cu-I-cyano links give rise to [Cu-CN](infinity) chains running along the c axis, which are bridged by bidentate PyzNH(2) ligands. The three-dimensional framework can be described as being formed by two interpenetrated three-dimensional honeycomb-like networks, both made of 26-membered rings of composition [Cu-6(mu-CN)(2)(mu-PyzNH(2))(4)].

DOI
10.1107/S010827010800231X
Citation Information
Silvina Pagola, Robert D Pike, Kathryn deKrafft and Tristan A Tronic. "Poly[mu-2-aminopyrazine-kappa N-2(1): N-4-mu-cyanido-copper(I)]: a three-dimensional network from laboratory powder diffraction data" ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS Vol. 64 (2008)
Available at: http://works.bepress.com/robert-pike/150/